MINERALS INDEX

Actinolite

Albite

Allactite

Allanite

Amphibole Group

Andradite

Anglesite

Anhydrite

Anorthite

Apatite

ApatiteGroup

Apophyllite

Aragonite

Arsenates

Arsenides

Arseniosiderite

Arsenopyrite

Aurichalcite

Axinite

Azurite

Barite

Barylite

Barysilite

Bementite

Biotite

Borates

Bornite

Boroarsenates

Bustamite

Cahnite

Calamine

Calcite

Calcium larsenite

Carbonates

Celestite

Cerusite

Chalcocite

Chalcophanite

Chalcopyrite

Chloanthite

Chlorite

Chlorophoenicite

Chondrodite

Chysolite Group

Clinohedrite

Copper

Corundum

Corundum Group

Crocidolite

Cummingtonite

Cuprite

Cuspidine

Cyprine

Datolite

Desaulesite

Descloizite

Diopside

Dolomite

Edenite

Epidote

EpidoteGroup

FeldsparGroup

Ferroaxinite

Ferroschallerite

Fluoborite

Fluorite

Franklinite

Friedelite

Friedelite Group

Gageite

Gahnite

Galena

Ganophyllite

Garnet

Glaucochroite

Goethite

Graphite

Greenockite

Gypsum

Halloysite

Haloids

Hancockite

Hardystonite

Hastingsite

Hedyphane

Hematite

Hetaerolite

Heulandite

Hodgkinsonite

Holdenite

Humite Group

Hyalophane

Hydrohetaerolite

Hydrozincite

Ilmenite

Jeffersonite

Kentrolite

Larsenite

Lead

Leucaugite

Leucophoenicite

Limonite

Lollingite

Loseyite

Magnesium- chlorophoenicite

Magnetite

Malachite

Manganbrucite

Manganite

Manganosite

Marcasite

Margarosanite

Mcgovernite

Mica Group

Microcline

Millerite

Molybdenite

Mooreite

Muscovite

Nasonite

Native Elements

Neotocite

Niccolite

Norbergite

Oxides

Pargasite

Pectolite

Phlogopite

Phosphates, Arsenates and Vanadates

Prehnite

Psilomelane

Pyrite

Pyrochroite

Pyroxene Group

Pyrrhotite

Quartz

Rhodochrosite

Rhodonite

Roeblingite

Roepperite

Rutile

Scapolite

Schallerite

Schefferite

Serpentine

Serpentine Group

Siderite

Silicates

Silver

Smithsonite

Sphalerite

Spinel

Spinel Group

Stilbite

Sulphates

Sulphides and Arsenides

Sussexite

Svabite

Talc

Tennantite

Tephroite

Thomsonite

Thorite

Titanite

Tourmaline

Tremolite and Actinolite

Unconfirmed Species

Vanadates

Vesuvianite

Willemite

Xonotlite

Zeolites

Zinc schefferite

Zincite

Zircon

Zoisite

 

Friedelite

Mn8(OH,Cl)4(SiO3)6.3H2O
Hexagonal-rhombohedral-hemimorphic

Forms
Positive pole: c(0001), q(4045), and m1(0110).
Negative pole: r1(1011), s1(15.0.15.2), and t1(0.15.15.2).

[Combinations on crystals of friedelite]

Crystallography
Friedelite crystals have been described heretofore only from Harstigen, Sweden. They are rather rough but were measured by Flink and show no trace of hemimorphism. His value for c = 0.5317, based on measurement of the unit rhombohedron, is here accepted. All the crystals are implanted by an end, and the free end was taken as the positive pole.

[Partial angle table of friedelite]

The rhombohedron t1 clearly truncates symmetrically the rhombohedron s1 of the opposite sign and gave better readings than s1, which was assumed to be the form previously determined by Flink, although the readings agree but poorly with it. In no crystal was any measurable face except the base and the rhombohedron q seen on the free end. The base is generally plane, brilliant, and sharply triangular in outline, but the crystals analyzed by Schaller were hexagonal.

Habit
Friedelite is found in markedly hemimorphic crystals, generally as minute tables but rarely in slender needles. The basal pinacoid is brilliant, but the other crystal faces are dull and give poor reflections on the goniometer. Friedelite is also found in fibrous aggregates coating other minerals or forming stalactites, in lamellar aggregates, and in cryptocrystalline massive form filling veins.

Composition
Friedelite is a hydrous basic manganese silicate generally containing more or less chlorine in place of part of the hydroxyl, as shown by some of the analyses. The computed composition of the chlorine-free mineral and that of the mineral with a normal amount of chlorine are also given in the table. The arsenic trioxide found in one analysis may be regarded as derived from a small amount of included schallerite.

The composition of friedelite and its relation to other members of the group have been treated by Bauer and Berman (260). The following statement is abstracted from their paper.

The formula of friedelite as given by Groth, by Dana, and by Palache (195), is in the orthosilicate form, but Zambonini and later Aminoff considered the mineral as metasilicate, as did Gage, Larsen, and Vassar (233) in comparing the composition of schallerite with that of friedelite. The metasilicate formula appears to give simpler results for the group and is here adopted. The orthosilicate formula of Palache converted into a metasilicate form becomes Mn8(OH,Cl)4(SiO3)6.3H2O.

[Analyses of friedelite]

Occurrence
Friedelite was first identified among the Franklin minerals by the author (195) on a specimen in the Kemble collection, found by Mr. Kemble many years ago in the Buckwheat mine. The mineral covers a surface of 2 or 3 square inches of massive granular franklinite-willemite ore and is apparently part of one wall of a thin transverse vein. The friedelite, massive beneath the surface and in tiny crystals on it, is largely covered with a botryoidal coating of magnesian. calcite which, in turn, bears on its surface a few platy crystals of barite. The specimen has the appearance of rhodochrosite, for which it was at first mistaken. It is now in the Harvard mineral collection.

Friedelite was also identified in extremely small amounts in two small specimens in the Canfield collection. It had the same form as that already described—flattened crystals, with narrow rhombohedral faces and no evidence of hemimorphism, in that respect being like the friedelite found in Europe.

A remarkable specimen of friedelite, now in the Hancock collection at Harvard University, was found in 1909 in the Taylor mine. The specimen contains a triangular cavity, 1-½ by ½ by ½ inch, shown in plate 14, C. The walls consist of a dark-green slickensided chloritic mineral mixed with magnetite, on which is a lining of more definite crystals, set edgewise, of the same chloritic substance. Within the cavity are white tetrahedrons of sphalerite as much as a quarter of an inch on an edge; rhodochrosite in platy rhombohedrons lines one inner surface and massive granular yellow friedelite another; and upon the massive friedelite and last to form in the cavity are implanted crystals of friedelite, which are sharply hemimorphic, the largest being not quite half an inch in diameter, and each is attached to the wall by the rhombohedral end, with a brilliantly lustrous base as the tipper termination. These crystals are the first on which evidence of hemimorphism had been seen (figure 133).

fig133.gif (4094 bytes)

Figure 133     Tabular hemimorphic crystal of friedelite showing at the positive pole the form c(0001) and at the negative pole the forms r1(1011), and m1(0110). Franklin.

On a part of the same specimen, belonging to Mr. Gage, tiny crystals of friedelite were completely embedded in barite, from which they were easily removed uninjured. Though rough and striated they yielded the measurements recorded here. One of them is shown in figure 134. A part of the massive friedelite lining this specimen was analyzed by Gage. (See analysis 5.)

Figure 134
Stout prismatic crystal of friedelite, showing at the positive pole the forms c(0001) and q(4045), and at the negative pole the forms c1(0001) (as cleavage), and s
1(15.0.15.2), and t1(0.15.15.2). Franklin.
fig134.gif (5597 bytes)

Since 1910 numerous specimens of friedelite have been found at Franklin, representing a variety of forms and associations. Fibrous crusts of a dark-red form of the mineral are associated with the fine crystals of tephroite that were found in 1915. (See page 77.) In the Harvard mineral collection there are, besides the specimens already described, one showing films of dark-red friedelite in columnar masses cutting massive garnet with later calcite and willemite, another showing granular yellow friedelite in patches in massive light-green willemite, and another showing a light-yellow crust of crystalline friedelite covering the bases of crystals of green willemite.

Solid veins of compact friedelite as much as 2 inches thick have been found since 1925. In the Stanton collection there were abundant specimens of pale-red friedelite showing thin veins with many cavities, their walls lined with tiny crystals. These specimens came from the 200-foot level south in the footwall pillar 854.

Analysis 4 in the table was made on this material. The crystals are similar to those of figure 134 but lack the positive rhombohedron q. Calcite and barite are the only associated minerals in these veins.

In another group of specimens veins of compact brown friedelite have open spaces whose walls are covered with light-yellow crystalline crusts. Although not measurable, the slender needles are clearly hemimorphic and are well represented by figure 135, except that they appear more slender. With them are the hematite crystals described on page 42.

Figure 135
Slender hemimorphic crystal of friedelite showing the form c(0001) at the positive pole; the forms c1(0001), as cleavage, and s
1(15.0.15.2) at the negative pole; and m1(0110).
fig135.gif (5269 bytes)

At Sterling Hill friedelite has also been found forming veins and stringers and mixed with calcite, cutting the massive ore. It is of lively pink color and is mostly compact but with scattered drusy cavities. A specimen from the 1,300-foot level, stope 720, with a specific gravity of 3.014, was analyzed by Mr. Bauer. Although it differs somewhat in composition from the other analyzed material in its high magnesia and alumina, it is undoubtedly to be regarded as a low chlorine friedelite.

 


 
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