MINERALS INDEX

Actinolite

Albite

Allactite

Allanite

Amphibole Group

Andradite

Anglesite

Anhydrite

Anorthite

Apatite

ApatiteGroup

Apophyllite

Aragonite

Arsenates

Arsenides

Arseniosiderite

Arsenopyrite

Aurichalcite

Axinite

Azurite

Barite

Barylite

Barysilite

Bementite

Biotite

Borates

Bornite

Boroarsenates

Bustamite

Cahnite

Calamine

Calcite

Calcium larsenite

Carbonates

Celestite

Cerusite

Chalcocite

Chalcophanite

Chalcopyrite

Chloanthite

Chlorite

Chlorophoenicite

Chondrodite

Chysolite Group

Clinohedrite

Copper

Corundum

Corundum Group

Crocidolite

Cummingtonite

Cuprite

Cuspidine

Cyprine

Datolite

Desaulesite

Descloizite

Diopside

Dolomite

Edenite

Epidote

EpidoteGroup

FeldsparGroup

Ferroaxinite

Ferroschallerite

Fluoborite

Fluorite

Franklinite

Friedelite

Friedelite Group

Gageite

Gahnite

Galena

Ganophyllite

Garnet

Glaucochroite

Goethite

Graphite

Greenockite

Gypsum

Halloysite

Haloids

Hancockite

Hardystonite

Hastingsite

Hedyphane

Hematite

Hetaerolite

Heulandite

Hodgkinsonite

Holdenite

Humite Group

Hyalophane

Hydrohetaerolite

Hydrozincite

Ilmenite

Jeffersonite

Kentrolite

Larsenite

Lead

Leucaugite

Leucophoenicite

Limonite

Lollingite

Loseyite

Magnesium- chlorophoenicite

Magnetite

Malachite

Manganbrucite

Manganite

Manganosite

Marcasite

Margarosanite

Mcgovernite

Mica Group

Microcline

Millerite

Molybdenite

Mooreite

Muscovite

Nasonite

Native Elements

Neotocite

Niccolite

Norbergite

Oxides

Pargasite

Pectolite

Phlogopite

Phosphates, Arsenates and Vanadates

Prehnite

Psilomelane

Pyrite

Pyrochroite

Pyroxene Group

Pyrrhotite

Quartz

Rhodochrosite

Rhodonite

Roeblingite

Roepperite

Rutile

Scapolite

Schallerite

Schefferite

Serpentine

Serpentine Group

Siderite

Silicates

Silver

Smithsonite

Sphalerite

Spinel

Spinel Group

Stilbite

Sulphates

Sulphides and Arsenides

Sussexite

Svabite

Talc

Tennantite

Tephroite

Thomsonite

Thorite

Titanite

Tourmaline

Tremolite and Actinolite

Unconfirmed Species

Vanadates

Vesuvianite

Willemite

Xonotlite

Zeolites

Zinc schefferite

Zincite

Zircon

Zoisite

 

Franklinite

(Fe,Mn,Zn)O.(Fe,Mn)2O3
Isometric

Forms
a(100), o(111), d(110), m(311), n(211), f(310), e(510), v(531), and doubtfully q(331) and p(221)

[Combinations on crystals of franklinite]

Habit
Franklinite occurs in crystals, dominantly octahedral, m isolated grains, and in coarse to fine or compact, massive granular form. Many crystals show narrow faces of the dodecahedron on edges of the octahedron, and on some the dodecahedron is dominant, but all show the octahedron more or less developed. More rarely faces of the trapezohedron m(311) appear, generally small but on some crystals in balance with the octahedron. The trapezohedron n(211) was seen on only one crystal but there with distinct faces. The trisoctahedron q(331) was also found but once, with narrow rounded faces between the octahedron and the dodecahedron. The trisoctahedron p(221), given by Dana, was not seen by the author on any crystal, and no published record of its observation was found.

An entirely aberrant habit was observed on two or three specimens, the best of which are in the Hancock collection. Their exact source is not known but is believed to have been the Hamburg mine at Franklin. These crystals, which do not exceed a tenth of an inch in diameter, are cubo-octahedrons with a few faces of the forms d, m, n, and f (figure 43).

Figure 43
Crystal of franklinite showing the octahedron, cube, and dodecahedron, and some faces of the forms m (311), n(211), and f(310). Hamburg mine.
fig43.gif (5035 bytes)

They are of adamantine luster, and thin splinters are translucent, with a deep-red color. Their unique habit and general spinelloid appearance suggested a new type of spinel, but the analysis (no. 16, page 47) showed the normal composition of franklinite. Crystallized with them on the walls of cavities in massive calcite-franklinite ore are prisms of pale-yellow willemite and white sphalerite.

In 1913 a small cavity was discovered by Mr. McGovern, of Franklin, in which were brilliant crystals of this type, showing a new form in two habits. This form is the tetrahexahedron e(510), established by the measurements of Phillips (211). In one habit e is combined with the cube alone (figure 45); in the other with the cube and the octahedron, all three forms being about equally developed (figure 46).

Figure 45
A cubic crystal of franklinite, showing only the cube and the tetrahexahedron e(510) Franklin.
fig45.gif (5590 bytes)
fig46.gif (7259 bytes) Figure 46
Crystal of franklinite showing the cube, the octahedron, and the tetrahexahedron e(510). Franklin.

These crystals are of splendent luster and ideal symmetry. They are associated with excellent crystals of willemite and tiny rosettes of talc, in a matrix of cavernous gray dolomite.

Small cubic crystals showing the forms of figure 44 were found on the walls of a cavity containing leucophoenicite, with the faces etched but still measurable.

Figure 44
A cubic crystal of franklinite, showing also the dodecahedron, the octahedron, and the trapezohedron m(311). Hamburg mine.
fig44.gif (6316 bytes)

The cubic habit for franklinite appears to be characteristic only for those rare specimens where it has crystallized in an open cavity, under pneumatolytic conditions.

Rounding of the crystal edges and angles is almost universal, the crystals passing thus into rounded grains. On some of the rounded crystals the apparently curved surfaces are made up of a multitude of facets, and measurement of some such crystals showed that the facets are either vicinal faces with highly complex symbols or are contact surfaces due to growth against the enclosing limestone. In one specimen, however, from the Canfield collection, a mass of limestone containing several crystals as much as an inch in diameter, the crystals yielded measurements showing positively the presence of the hexoctahedron v(531), a characteristic magnetite form.

Figure 47
Crystal of franklinite showing the octahedron, the dodecahedron, the trapezohedron m(311), and the rare hexoctahedron v(531). Sterling Hill.
fig47.gif (10116 bytes)

Physical characters
An octahedral parting is marked in some material but is generally absent. The hardness is 5.5 to 6.5, and the specific gravity is 5.07 to 5.22. The color is black, rarely with an iridescent coating, and the luster is brilliant metallic to dull. The streak and thin fragments are reddish brown, (See, however, the description of the unusual phase on page 45.) Index of refraction, nLi = 2.36 ±0.02. The magnetism in some material, to which the local name of "magnofranklinite" was given by Canfield, is as strong as that of magnetite, but other material is not sensibly affected by a pocket magnet. This difference probably depends on the relative amount of ferrous iron present, and all varieties are strongly attracted by the electromagnets in the separating machines.

Composition
Although conforming to the spinel formula, the composition of franklinite shows a wide range, both in the relative proportions of iron, manganese, and zinc and in the state of oxidation of the iron and manganese. Although but one analysis in the following table actually records the presence of ferrous iron, the ordinary magnetism of the substance leads to the conviction that some ferrous iron is usually present; its accurate determination is impossible in the presence of manganous and manganic oxides.3 Manganese is probably present in both states of oxidation, and the general formula given at the head of this description probably applies to most specimens of the mineral. Special tests for titanium made on samples of franklinite from different parts of the deposit showed its presence only in traces.
    3 Schaller, W. T., personal communication.

[Analyses of franklinite]

Occurrence
Franklinite is the dominant mineral of the ore body at Franklin, either forming thick beds free from any other material or mixed with various amounts of calcite, willemite, zincite, or rhodonite. It is commonly granular, as shown in plate 7, B, or in isolated grains. Crystals are rare and are confined chiefly to parts of the ore body which appear to have undergone recrystallization, the ore constituents being embedded in calcite. In such places the crystals are likely to be very sharply formed and of brilliant luster. Such crystals, scarcely more than half an inch in diameter and with most brilliant luster, were not rare in material from the Parker shaft. At the Trotter mine slightly larger crystals, as much as 1-½ inches in diameter, were found. They show a tendency toward the dodecahedral habit, and some dodecahedrons are striated like magnetite, parallel to the intersection edge with the octahedron, the faces being dull. Many similar groups, taken from the Buckwheat and Taylor mines, were also seen.

Figure 39
Crystal of franklinite showing the octahedron with a narrow truncation by the dodecahedron—a common type.
fig39.gif (6029 bytes)
fig40.gif (8208 bytes) Figure 40
Crystal of franklinite showing the octahedron in balance with a trapezohedron, m(311), and small faces of the dodecahedron.

At Sterling Hill also franklinite is the dominant ore mineral and occurs prevailingly in granular masses. In the first explorations of the mines, however, at the very surface, crystals of extraordinary dimensions were found, the best of which are now preserved in the Canfield collection. Several of the finest are illustrated in plate 6, A, B. The crystals shown in the photographs are octahedrons, alone or with slight modification by the dodecahedron, measuring 7 inches or less on an edge. They are attached to massive franklinite and with them is troostite in dull, lusterless crystals. They are said to have been embedded in dark-brown or black claylike material or wad, presumably the residue left from solution of the manganiferous limestone in which they wore originally developed. They are of dull luster but of wonderfully perfect form.

From the Noble mine also came many dodecahedral crystals of nearly perfect form, dull and somewhat rounded as if etched, with small or no octahedral faces and very rarely the faces of the trapezohedron m(311). One of them is shown in plate 7, A. Much of this material was almost wholly lacking in zinc and was correspondingly rich in ferrous iron. This was the so-called "magnofranklinite" and was used as an ore of iron and manganese without previous roasting for zinc oxide. (See appendix, c, page 130.)

Figure 41
Crystal of franklinite showing the dodecahedron and the octahedron and small faces of the trapezohedron m(311).
fig41.gif (7431 bytes)
fig42.gif (7984 bytes) Figure 42
Crystal of franklinite showing the dodecahedron, the octahedron, and the trapezohedron n(211).

Lustrous octahedral crystals of franklinite with rounded angles, embedded in granular zincite, were also characteristic of much of the ore at Sterling Hill, especially of the outcrop of the front vein.

Figure 48
Dodecahedral crystal of franklinite modified and striated by the octahedron. Sterling Hill.
fig48.gif (10317 bytes)

Historical notes
Bruce, who, discovered the zinciferous nature of zincite, considered the black mineral associated with it to be magnetite. This it was generally supposed to be, and several unsuccessful efforts were made to work this refractory material as an ore of iron.

The true character of the mineral was first determined by the French chemist Berthier (3), who named it franklinite "in order to remind us that it was first found in a place to which the Americans have given the name of a great man." He gave an approximate analysis and the correct mineralogic characters.

Although thus early recognized as a distinct species, with a considerable content of zinc, it was for many years ignored as an ore of zinc, the whole attention of the zinc miners being given to the richer zincite. This oversight and the persistent consideration of franklinite as an ore of iron led to the peculiar division of mineral rights in the Franklin deposits into ores of zinc and ores of iron, which resulted in the long-fought lawsuits that for years retarded the development of the mines.

The value of franklinite as an ore of zinc was not recognized until later, when the invention by Wetherill of a furnace in which the zinc could be roasted off to form zinc white revolutionized the local practice, and the further improvement in treatment brought about by the perfection of the magnetic separator established it as the major zinc ore of the district.

 


 
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