MINERALS INDEX
Franklinite |
| (Fe,Mn,Zn)O.(Fe,Mn)2O3 |
| Isometric |
Forms
a(100), o(111), d(110), m(311), n(211),
f(310), e(510), v(531), and doubtfully q(331)
and p(221)
[Combinations on crystals of franklinite]
Habit
Franklinite occurs in crystals, dominantly
octahedral, m isolated grains, and in coarse to fine or compact, massive
granular form. Many crystals show narrow faces of the dodecahedron on
edges of the octahedron, and on some the dodecahedron is dominant, but
all show the octahedron more or less developed. More rarely faces of the
trapezohedron m(311) appear, generally small but on some crystals
in balance with the octahedron. The trapezohedron n(211) was seen
on only one crystal but there with distinct faces. The trisoctahedron
q(331) was also found but once, with narrow rounded faces between
the octahedron and the dodecahedron. The trisoctahedron p(221),
given by Dana, was not seen by the author on any crystal, and no published
record of its observation was found.
An entirely aberrant habit was observed on two or three specimens, the best of which are in the Hancock collection. Their exact source is not known but is believed to have been the Hamburg mine at Franklin. These crystals, which do not exceed a tenth of an inch in diameter, are cubo-octahedrons with a few faces of the forms d, m, n, and f (figure 43).
| Figure
43 Crystal of franklinite showing the octahedron, cube, and dodecahedron, and some faces of the forms m (311), n(211), and f(310). Hamburg mine. |
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They are of adamantine luster, and thin splinters are translucent, with a deep-red color. Their unique habit and general spinelloid appearance suggested a new type of spinel, but the analysis (no. 16, page 47) showed the normal composition of franklinite. Crystallized with them on the walls of cavities in massive calcite-franklinite ore are prisms of pale-yellow willemite and white sphalerite.
In 1913 a small cavity was discovered by Mr. McGovern, of Franklin, in which were brilliant crystals of this type, showing a new form in two habits. This form is the tetrahexahedron e(510), established by the measurements of Phillips (211). In one habit e is combined with the cube alone (figure 45); in the other with the cube and the octahedron, all three forms being about equally developed (figure 46).
| Figure
45 A cubic crystal of franklinite, showing only the cube and the tetrahexahedron e(510) Franklin. |
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Figure
46 Crystal of franklinite showing the cube, the octahedron, and the tetrahexahedron e(510). Franklin. |
These crystals are of splendent luster and ideal symmetry. They are associated with excellent crystals of willemite and tiny rosettes of talc, in a matrix of cavernous gray dolomite.
Small cubic crystals showing the forms of figure 44 were found on the walls of a cavity containing leucophoenicite, with the faces etched but still measurable.
| Figure
44 A cubic crystal of franklinite, showing also the dodecahedron, the octahedron, and the trapezohedron m(311). Hamburg mine. |
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The cubic habit for franklinite appears to be characteristic only for those rare specimens where it has crystallized in an open cavity, under pneumatolytic conditions.
Rounding of the crystal edges and angles is almost universal, the crystals passing thus into rounded grains. On some of the rounded crystals the apparently curved surfaces are made up of a multitude of facets, and measurement of some such crystals showed that the facets are either vicinal faces with highly complex symbols or are contact surfaces due to growth against the enclosing limestone. In one specimen, however, from the Canfield collection, a mass of limestone containing several crystals as much as an inch in diameter, the crystals yielded measurements showing positively the presence of the hexoctahedron v(531), a characteristic magnetite form.
| Figure
47 Crystal of franklinite showing the octahedron, the dodecahedron, the trapezohedron m(311), and the rare hexoctahedron v(531). Sterling Hill. |
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Physical characters
An octahedral parting is marked in some material but is generally absent.
The hardness is 5.5 to 6.5, and the specific gravity is 5.07 to 5.22.
The color is black, rarely with an iridescent coating, and the luster
is brilliant metallic to dull. The streak and thin fragments are reddish
brown, (See, however, the description of the unusual phase on page
45.) Index of refraction, nLi = 2.36 ±0.02. The
magnetism in some material, to which the local name of "magnofranklinite"
was given by Canfield, is as strong as that of magnetite, but other
material is not sensibly affected by a pocket magnet. This difference
probably depends on the relative amount of ferrous iron present, and
all varieties are strongly attracted by the electromagnets in the separating
machines.
Composition
Although conforming to the spinel formula, the composition of franklinite
shows a wide range, both in the relative proportions of iron, manganese,
and zinc and in the state of oxidation of the iron and manganese. Although
but one analysis in the following table actually records the presence
of ferrous iron, the ordinary magnetism of the substance leads to the
conviction that some ferrous iron is usually present; its accurate determination
is impossible in the presence of manganous and manganic oxides.3
Manganese is probably present in both states of oxidation, and the general
formula given at the head of this description probably applies to most
specimens of the mineral. Special tests for titanium made on samples
of franklinite from different parts of the deposit showed its presence
only in traces.
3 Schaller, W. T., personal communication.
Occurrence
Franklinite is the dominant mineral of the ore body at Franklin, either
forming thick beds free from any other material or mixed with various
amounts of calcite, willemite, zincite, or rhodonite. It is commonly
granular, as shown in plate 7, B,
or in isolated grains. Crystals are rare and are confined chiefly to
parts of the ore body which appear to have undergone recrystallization,
the ore constituents being embedded in calcite. In such places the crystals
are likely to be very sharply formed and of brilliant luster. Such crystals,
scarcely more than half an inch in diameter and with most brilliant
luster, were not rare in material from the Parker shaft. At the Trotter
mine slightly larger crystals, as much as 1-½ inches in diameter, were
found. They show a tendency toward the dodecahedral habit, and some
dodecahedrons are striated like magnetite, parallel to the intersection
edge with the octahedron, the faces being dull. Many similar groups,
taken from the Buckwheat and Taylor mines, were also seen.
| Figure
39 Crystal of franklinite showing the octahedron with a narrow truncation by the dodecahedrona common type. |
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Figure
40 Crystal of franklinite showing the octahedron in balance with a trapezohedron, m(311), and small faces of the dodecahedron. |
At Sterling Hill also franklinite is the dominant ore mineral and occurs prevailingly in granular masses. In the first explorations of the mines, however, at the very surface, crystals of extraordinary dimensions were found, the best of which are now preserved in the Canfield collection. Several of the finest are illustrated in plate 6, A, B. The crystals shown in the photographs are octahedrons, alone or with slight modification by the dodecahedron, measuring 7 inches or less on an edge. They are attached to massive franklinite and with them is troostite in dull, lusterless crystals. They are said to have been embedded in dark-brown or black claylike material or wad, presumably the residue left from solution of the manganiferous limestone in which they wore originally developed. They are of dull luster but of wonderfully perfect form.
From the Noble mine also came many dodecahedral crystals of nearly perfect form, dull and somewhat rounded as if etched, with small or no octahedral faces and very rarely the faces of the trapezohedron m(311). One of them is shown in plate 7, A. Much of this material was almost wholly lacking in zinc and was correspondingly rich in ferrous iron. This was the so-called "magnofranklinite" and was used as an ore of iron and manganese without previous roasting for zinc oxide. (See appendix, c, page 130.)
| Figure
41 Crystal of franklinite showing the dodecahedron and the octahedron and small faces of the trapezohedron m(311). |
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Figure
42 Crystal of franklinite showing the dodecahedron, the octahedron, and the trapezohedron n(211). |
Lustrous octahedral crystals of franklinite with rounded angles, embedded in granular zincite, were also characteristic of much of the ore at Sterling Hill, especially of the outcrop of the front vein.
| Figure
48 Dodecahedral crystal of franklinite modified and striated by the octahedron. Sterling Hill. |
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Historical notes
Bruce, who, discovered the zinciferous nature of zincite, considered
the black mineral associated with it to be magnetite. This it was generally
supposed to be, and several unsuccessful efforts were made to work this
refractory material as an ore of iron.
The true character of the mineral was first determined by the French chemist Berthier (3), who named it franklinite "in order to remind us that it was first found in a place to which the Americans have given the name of a great man." He gave an approximate analysis and the correct mineralogic characters.
Although thus early recognized as a distinct species, with a considerable content of zinc, it was for many years ignored as an ore of zinc, the whole attention of the zinc miners being given to the richer zincite. This oversight and the persistent consideration of franklinite as an ore of iron led to the peculiar division of mineral rights in the Franklin deposits into ores of zinc and ores of iron, which resulted in the long-fought lawsuits that for years retarded the development of the mines.
The value of franklinite as an ore of zinc was not recognized until later, when the invention by Wetherill of a furnace in which the zinc could be roasted off to form zinc white revolutionized the local practice, and the further improvement in treatment brought about by the perfection of the magnetic separator established it as the major zinc ore of the district.
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© by Herb Yeates 1997-2001.
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